ALIGNMENT DETECTED PHOTOFRAGMENT YIELD SPECTROSCOPY DEMONSTRATED BY PBOTODISSOCIATION OF T-BUTYLNITRITE IN A SUPERSONIC JET

Authors
ROSSLEIN M KADES E BERGMANN K HUBER JR
Citation
M. Rosslein et al., ALIGNMENT DETECTED PHOTOFRAGMENT YIELD SPECTROSCOPY DEMONSTRATED BY PBOTODISSOCIATION OF T-BUTYLNITRITE IN A SUPERSONIC JET, Chemical physics letters, 235(3-4), 1995, pp. 242-246
Citations number
26
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics letters → ACNP
ISSN journal
00092614
Volume
235
Issue
3-4
Year of publication
1995
Pages
242 - 246
Database
ISI
SICI code
0009-2614(1995)235:3-4<242:ADPYSD>2.0.ZU;2-Z
Abstract
Alignment detected, state-specific photofragment yield spectroscopy is introduced and demonstrated for the S-1 photodissociation of t-butyln itrite (CH3)(3)CO-N=O. For this process the rotational alignment A(0)( (2)) of the nascent NO fragment is shown to depend on the initially ex cited vibronic state of the parent molecule.