THERMOGRAVIMETRIC STUDY OF THE PYROLYSIS OF BEECH WOOD AND WEIGHT-LOSS KINETICS BASED ON FIRST-ORDER SINGLE REACTION MODEL

Citation
M. Nikazar et al., THERMOGRAVIMETRIC STUDY OF THE PYROLYSIS OF BEECH WOOD AND WEIGHT-LOSS KINETICS BASED ON FIRST-ORDER SINGLE REACTION MODEL, Afinidad, 52(455), 1995, pp. 19-24
Citations number
9
Categorie Soggetti
Chemistry
Journal title
ISSN journal
00019704
Volume
52
Issue
455
Year of publication
1995
Pages
19 - 24
Database
ISI
SICI code
0001-9704(1995)52:455<19:TSOTPO>2.0.ZU;2-7
Abstract
The kinetics of weight loss in the thermal decomposition of Beech Wood , in helium gas atmosphere, has been studied by thermogravimetry with particles having 53-63 microns average size and applying a heating rat e of 50-100 degrees C/min to final temperature of 1000 degrees C. A fi rst order pathway reaction was assumed and based on linear heating, th e parameters of the model (Arrhenius pre-exponential factor apparent a ctivation energy and ultimate value of weight loss at high temperature and long residence time) were found to be 9.693-10(3-1) s, 16500 cal/ gmol and 86.797% respectively. A good agreement was observed between t he experimental results and those predicted from the model.