The microstructure of weld metals of 2.25Cr-1Mo, 5Cr-0.5Mo, 9Cr-1Mo an
d 12Cr-1Mo type steels was studied with electron microscopy and atom p
robe field ion microscopy. Many different types of carbides and nitrid
es precipitated during welding and post-weld heat treatment (MC, M(2)C
, M(3)C, M(7)C(3), M(23)C(6), MN, M(2)N). The eutectoid decomposition
of retained austenite gave large aggregates of carbides which were fou
nd to be detrimental to the impact toughness of the weld metal.