M. Devel et al., FIELD-INDUCED MANIPULATION OF FULLERENE MOLECULES WITH THE STM - A SELF-CONSISTENT THEORETICAL-STUDY, Applied surface science, 87-8(1-4), 1995, pp. 390-397
Citations number
24
Categorie Soggetti
Physics, Condensed Matter","Chemistry Physical","Materials Science, Coatings & Films
By applying an appropriate voltage between an STM tip and a metallic s
ubstrate, it is possible to induce highly localized electrostatic fiel
ds. In this paper, it is shown that the apex of the STM probe, respons
ible for the resolution, confines an electric field of small lateral e
xtension inside the junction. The change in the potential energy of an
adsorbate submitted to such a field is calculated with a self-consist
ent scheme. A microscopic description of both the tip-apex and the ads
orbates is used and the correlations between each polarizable centre a
re accounted for with a discretized Lippmann-Schwinger equation. Sever
al applications show that our real space approach is extremely attract
ive for studying electrostatic field distributions in low symmetry sys
tems. Field induced manipulation processes of C-60 molecules are discu
ssed in this context.