Pyridine-pendent siloxane polymers containing a backbone modified with
a zirconocene moiety were synthesized through the hydrolysis-condensa
tion reaction of the mixed precursor solutions of the beta-trimethoxys
ilylethyl-2-pyridine sol in liquor medium and the zirconocene dichlori
de (Cp(2)ZrCl(2)) dissolved in tetrahydrofurane. This polymer, in term
s of the polyzirconocenesiloxane-2-pyridine (PZSP), was then evaluated
for use as thin coating films (thickness, 0.5-1.0 mu m), which provid
es excellent protection of aluminum (A1) alloys against NaCl-caused co
rrosion. The PZSP films deposited by simple dip-withdrawing coating me
thods to A1 displayed the impedance of > 10(6) Omega cm(2) after expos
ure for 40 days in 0.5 N NaCl solution at 15 degrees C and 3000 h salt
-spray resistance.