ORGANOMETALLIC PHOSPHAZENES - SYNTHESIS AND CHARACTERIZATION OF PT(II) AND PT(0) CINNAMMONITRILE CYCLOPHOSPHAZENE DERIVATIVES

Authors
BELLUCO U BERTANI R MICHELIN RA MOZZON M ZINGALES F GLERIA M
Citation
U. Belluco et al., ORGANOMETALLIC PHOSPHAZENES - SYNTHESIS AND CHARACTERIZATION OF PT(II) AND PT(0) CINNAMMONITRILE CYCLOPHOSPHAZENE DERIVATIVES, Inorganica Chimica Acta, 229(1-2), 1995, pp. 13-15
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
229
Issue
1-2
Year of publication
1995
Pages
13 - 15
Database
ISI
SICI code
0020-1693(1995)229:1-2<13:OP-SAC>2.0.ZU;2-O
Abstract
Hexakis (4-formylphenoxy)cyclophosphazene has been reacted with (cyano methylene)triphenyl phosphorane to yield the hexakis(4-cinnammonitrile phenoxy)cyclophosphazene compound. The cinnammonitrile moieties have been used to bind six ({PPh(3))(2)Pt} fragments on the olefin groups, six trans-{Pt(PPh(3))(2)(CF3)} to the nitrile groups and both Pt(0) an d Pt(II) groups to yield compounds 2, 3 and 4, respectively.