Carboniferous rocks in the north Solway onshore outcrop show evidence
of hydrocarbon migration. Oil residues occur as intergranular bitumen
in sandstones, thoriferous bitumen nodules in sandstones and uranifero
us bitumens in fractures associated with the North Solway Fault at the
northern margin of the Solway Basin. Oil was emplaced in sandstones a
fter the dissolution of dolomite, calcite and clay cements. The radioe
lement-rich bitumens represent deposition following interactions betwe
en migrating hydrocarbons and metalliferous fluids. The close proximit
y of the Caledonian Criffel granodiorite, unroofed by Carboniferous ti
mes, suggests that the pluton was the source of uranium and thorium. H
ydrocarbon source rocks are identified further east in the more comple
te succession exposed in the Esk Valley region, along with further oil
residues. Time-temperature modelling suggests that oil was generated
from Lower Carboniferous source rocks during the Permo-Triassic. Chemi
cal age dating of uraninite in bitumen yields early Jurassic ages, whi
ch may reflect the time of hydrocarbon migration along the North Solwa
y Fault system, and may be related to a mid-Jurassic episode of region
al uplift. Analyses of thorite in bitumen nodules give a wider spread
of data, probably due to the migration of daughter lead.