M. Arai et al., STRUCTURAL EVOLUTION OF SPIN-PEIERLS MATERIAL CUGEO3 STUDIED BY NEUTRON-SCATTERING, Journal of magnetism and magnetic materials, 140, 1995, pp. 1689-1690
The crystal structure and phonon dynamics of the spin-Peierls material
CuGeO3 have been studied by neutron scattering. We found a large latt
ice anomaly in the a-b plane, perpendicular to the one-dimensional ant
iferromagnetic spin chain, above the transition temperature. The phono
n modes at 100 meV, of the chain oxygens, show anomalous behavior, con
sistent with structural change. We therefore conclude that the structu
ral evolution of the chain oxygens in the a-b plane, which mediates th
e spin-spin interaction along the c-axis, drives the spin-Peierls tran
sition.