THE INDUCED CIRCULAR-DICHROISM OF HELICALLY SHAPED RACEMIC BILATRIENES

Authors
KROIS D LEHNER H
Citation
D. Krois et H. Lehner, THE INDUCED CIRCULAR-DICHROISM OF HELICALLY SHAPED RACEMIC BILATRIENES, Monatshefte fuer Chemie, 126(3), 1995, pp. 349-354
Citations number
23
Categorie Soggetti
Chemistry
Journal title
Monatshefte fuer Chemie → ACNP
ISSN journal
00269247
Volume
126
Issue
3
Year of publication
1995
Pages
349 - 354
Database
ISI
SICI code
0026-9247(1995)126:3<349:TICOHS>2.0.ZU;2-X
Abstract
The imperfect mirror image relationship of the circular dichroism of ( M) and (P) helical biliverdins bound to a homochiral entity (ICD) has been studied using the kinetically stable racemates (M + P) 2 and (M P) 3. The phenomena associated with and eventual implications for the interpretation of ICD spectra of naturally occurring kinetically labi le biliverdins in terms of chiral recognition are discussed.