PALLADIUM-CATALYZED SUBSTITUTION OF ESTERS OF NAPHTHYLMETHANOLS, 1-NAPHTHYLETHANOLS, AND ANALOGS BY SODIUM DIMETHYL MALONATE - STEREOSELECTIVE SYNTHESIS FROM ENANTIOMERICALLY PURE SUBSTRATES

Authors
LEGROS JY TOFFANO M FIAUD JC
Citation
Jy. Legros et al., PALLADIUM-CATALYZED SUBSTITUTION OF ESTERS OF NAPHTHYLMETHANOLS, 1-NAPHTHYLETHANOLS, AND ANALOGS BY SODIUM DIMETHYL MALONATE - STEREOSELECTIVE SYNTHESIS FROM ENANTIOMERICALLY PURE SUBSTRATES, Tetrahedron, 51(11), 1995, pp. 3235-3246
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
51
Issue
11
Year of publication
1995
Pages
3235 - 3246
Database
ISI
SICI code
0040-4020(1995)51:11<3235:PSOEON>2.0.ZU;2-9
Abstract
The palladium-catalyzed substitution of carbonates of the titled alcoh ols was performed at lower temperature than the previously reported re action of the corresponding acetates. The use of enantiomerically pure carbonates gave substitution products with overall retention of the c onfiguration (up to 97%).