CHEMISTRY OF VINYLIDENE COMPLEXES .11. SYNTHESIS OF TRINUCLEAR MNFEPTCOMPLEXES BY MEANS OF CONSECUTIVE ASSEMBLING OUT OF MONOMETAL AND DIMETAL VINYLIDENE PRECURSORS
Ab. Antonova et al., CHEMISTRY OF VINYLIDENE COMPLEXES .11. SYNTHESIS OF TRINUCLEAR MNFEPTCOMPLEXES BY MEANS OF CONSECUTIVE ASSEMBLING OUT OF MONOMETAL AND DIMETAL VINYLIDENE PRECURSORS, Inorganica Chimica Acta, 230(1-2), 1995, pp. 97-104
The dimetal mu-vinylidene complexes Cp(CO)(2)MnPt(mu-C=CHPh)L(2) (L=te
rt.-phosphine or -phosphite), which have been obtained by coupling of
the mononuclear complex Cp(CO)(2)Mn=C=CHPh and unsaturated PtL(2) unit
, add smoothly the Fe(CO)(4) moiety to produce trimetal MnFePt compoun
ds. The mu(3)-vinylidene cluster CpMnFePt(mu(3)-C=CHPh)(CO)(6)(PPh(3))
was prepared in quantitative yields from the reactions of Cp(CO)(2)Mn
Pt(mu-C=CHPh)(PPh(3))L (L=PPh(3) or CO) with Fe-2(CO)(9) in benzene at
20 degrees C. The phosphite-substituted complexes Cp(CO)(2)Mnpt(mu-C=
CHph)L(2) (L=P(OEt)(3) or P(OPri)(3)) react under analogous conditions
with Fe-2(CO)(9) to give mixtures (2:3) of the penta- and hexacarbony
l clusters, CpMnFePt(mu(3)-C= CHPh)(CO)(5)L(2) and CpMnFePt(mu(3)-C=CH
Ph)(CO)(6)L, respectively. The similar reaction of the dimetal complex
Cp(CO)(2)MnPt(mu-C=CHPh)(dppm), in which the Pt atom is chelated by d
ppm=Ph(2)PCH(2)PPh(2) ligand, gives only a 15% yield of the analogous
trimetal mu(3)-vinylidene hexacarbonyl product CpMnFePt(mu(3)-C=CHPh)(
CO)(6)(dppm), but the major product (40%) is the tetranuclear mu(4)-vi
nylidene cluster (dppm)PtFe3(mu(4)-C=CHPh)(CO)(9). The IR and H-1, C-1
3 and P-31 NMR data for the new complexes are reported and discussed.