An approach to the assessment of fumes produced in laser material proc
essing is presented. The subsequent design of the fume containment sys
tem and sampling strategy is detailed. Polyvinyl chloride (PVC) has be
en selected for investigation and the complexity resulting from the pl
ethora of additives is discussed. Qualitative results from the prelimi
nary studies of CO2 laser cutting of PVC are presented together with a
n appraisal of the problems involved in extending this to quantitative
analysis. Benzene, hydrogen chloride (HCl) and methyl methacrylate we
re found to be the dominant emissions.