NITROSATION OF KETONE DIANIONS

Authors
IKEDA H HARAGUCHI T YUKAWA M NIIYA T GOTO Y
Citation
H. Ikeda et al., NITROSATION OF KETONE DIANIONS, Chemical and Pharmaceutical Bulletin, 43(3), 1995, pp. 526-528
Citations number
16
Categorie Soggetti
Pharmacology & Pharmacy",Chemistry
Journal title
Chemical and Pharmaceutical Bulletin → ACNP
ISSN journal
00092363
Volume
43
Issue
3
Year of publication
1995
Pages
526 - 528
Database
ISI
SICI code
0009-2363(1995)43:3<526:NOKD>2.0.ZU;2-Q
Abstract
Nitrosation of alpha,alpha'-dianions produced from ketones using a cou ple of bases was carried out with tert-butyl nitrite(tert-BuONO) in et her, and then two regioisomers of oximes(but not acetone)were obtained simultaneously. The ratio of these regioisomers was remarkably revers ed by the addition of hexamethylphosphoric triamide(HMPA).