THE CRYSTAL-STRUCTURE OF ZACYCLOTETRA-DECA-2,4,6,9,12,14-HEXAENATO(2-)-N-1, N-4, N-8, N-11]NICKEL(II) AND AZACYCLOTETRA-DECA-2,4,6,9,12,14-HEXAENATO(2)-N-1, N-4, N-8, N-11]NICKEL(II)

Authors
DVORKIN A BOUROSH P SIMONOV Y ARION V GRADINARU J GERBELEU N
Citation
A. Dvorkin et al., THE CRYSTAL-STRUCTURE OF ZACYCLOTETRA-DECA-2,4,6,9,12,14-HEXAENATO(2-)-N-1, N-4, N-8, N-11]NICKEL(II) AND AZACYCLOTETRA-DECA-2,4,6,9,12,14-HEXAENATO(2)-N-1, N-4, N-8, N-11]NICKEL(II), Polyhedron, 14(5), 1995, pp. 571-577
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
14
Issue
5
Year of publication
1995
Pages
571 - 577
Database
ISI
SICI code
0277-5387(1995)14:5<571:TCOZ>2.0.ZU;2-U
Abstract
Hexaazamocrocyclic complexes ,9,12,14-hexaenato(2-)-N-1,N-4,N-8,N-11]n ickel(II) and ,9,12,14-hexaenato(2-)-N-1,N-4,N-8,N-11]nickel(II) have been synthesized by a template procedure starting from an open-chain p recursor. The crystal structure of both macrocycle products showed a s quare planar coordination geometry with cis-positioned-SR groups relat ive to the nickel atom.