X-RAY CRYSTAL-STRUCTURE, SPECTRAL AND MAGNETIC-PROPERTIES OF A MIXED-LIGAND DINUCLEAR COMPLEX [CU(PHEN)(SA)(CLO4)](2)

Authors
LI M ZOU JZ XU Z YOU XZ HUANG XY
Citation
M. Li et al., X-RAY CRYSTAL-STRUCTURE, SPECTRAL AND MAGNETIC-PROPERTIES OF A MIXED-LIGAND DINUCLEAR COMPLEX [CU(PHEN)(SA)(CLO4)](2), Polyhedron, 14(5), 1995, pp. 639-642
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
14
Issue
5
Year of publication
1995
Pages
639 - 642
Database
ISI
SICI code
0277-5387(1995)14:5<639:XCSAMO>2.0.ZU;2-6
Abstract
The mixed-ligand dinuclear complex [Cu(Phen)(Sa)(ClO4)](2) (where Phen = 1,10-phenanthroline and Sa = salicylaldehyde) has been synthesized and characterized by IR and ESR spectra and magnetic susceptibility me asurements, which obey the Curie-Weiss law with theta = -10 K. The cry stal structure of the title complex has been determined and is a dimer in which two monomeric units are bridged by two oxygen atoms of pheno late groups.