MAGNETIC-PROPERTIES OF THE COBALTATES NA6 COS4, NA(6)COSE4, AND K6COS4

Authors
BRONGER W BOMBA C KOELMAN W
Citation
W. Bronger et al., MAGNETIC-PROPERTIES OF THE COBALTATES NA6 COS4, NA(6)COSE4, AND K6COS4, Zeitschrift fur anorganische und allgemeine Chemie, 621(3), 1995, pp. 409-411
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
621
Issue
3
Year of publication
1995
Pages
409 - 411
Database
ISI
SICI code
0044-2313(1995)621:3<409:MOTCNC>2.0.ZU;2-Z
Abstract
The alkali metal cobalt chalcogenides Na6CoS4, Na6CoSe4, and K6CoS4 cr ystallize in the space group P6(3)mc with Z = 4. The structure is char acterized by isolated [CoX(4)]-tetrahedra. The magnetic susceptibiliti es show Curie-Weiss behaviour. The deviations at low temperatures are caused by antiferromagnetic interactions. The magnetic moments are dis cussed with regard to ligand-field parameters.