BIS(DIPHENYLPHOSPHANO)ALKANE AND 1-DIPHEN PHOSPHANO-2-(2-PYRIDINO)ETHANE-N-ARYLSULFINYLAMINE NICKEL(0) COMPLEXES

Authors
WENSCHUH E HOFFMANN H WILHELM D
Citation
E. Wenschuh et al., BIS(DIPHENYLPHOSPHANO)ALKANE AND 1-DIPHEN PHOSPHANO-2-(2-PYRIDINO)ETHANE-N-ARYLSULFINYLAMINE NICKEL(0) COMPLEXES, Zeitschrift fur anorganische und allgemeine Chemie, 621(3), 1995, pp. 435-438
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
621
Issue
3
Year of publication
1995
Pages
435 - 438
Database
ISI
SICI code
0044-2313(1995)621:3<435:BA1P>2.0.ZU;2-K
Abstract
Synthesis and properties of the lphosphano)alkane-N-phenyl-sulfinylami ne-nickel(0) complexes [Ni(Ph(2)P(CH2)(n)PPh(2))(PhNSO)] (n = 2 dppe, n = 3 dppp, n = 4 dppb) as well as of the 1-(diphenylphosphano)-2-(2-p yridino)ethane nickel(0) complexes [Ni(dpppe)(2)], [Ni(dpppe)(p-TolNso )] and [Ni(dpppe)(PPh(3))(2)] are described. These compounds have been characterized by i.r. and P-31 n.m.r. spectroscopy. The N-arylsulfiny lamine ligands are eta(2)-(N,S)-side on coordinated.