Citation
M. Jansen et S. Strojek, SYNTHESES AND CHARACTERIZATION OF P4O7S, Zeitschrift fur anorganische und allgemeine Chemie, 621(3), 1995, pp. 479-483
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313
→ ACNP
Volume
621
Issue
3
Year of publication
1995
Pages
479 - 483
Database
ISI
SICI code
0044-2313(1995)621:3<479:SACOP>2.0.ZU;2-2
Abstract
P4O7S was synthesized for the first time and characterized by X-ray st
ructure determination (single-crystal methods) and P-31-n.m.r. (soluti
on and MAS-solid) (P $($) over bar$$ 1; a = 687.2(1); b = 718.2(1); c
= 809.1(1) pm; alpha = 92.58(1)degrees; beta = 104.43(1)degrees; gamma
= 94.82(2)degrees; 2907 diffractometer data; R(1) = 0.030; wR(2) = 0.
102). The different influences of terminally bound oxygen and sulfur o
n the geometry of the P4O6 cage are discussed.