A. Ruzicka et al., SYNTHESES AND STRUCTURES OF S4N4(OCH3)(2) AND CH3OS4N4(O)CL, Zeitschrift fur anorganische und allgemeine Chemie, 621(3), 1995, pp. 495-499
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
The reaction of S4N4Cl2 with CH3OH gives S4N4(OCH3)(2), a simple dimet
hoxoderivative of S4N4. Its overall geometry is analogous to other com
pounds of the S(4)N(4)X(2) type. The chlorination of S4N4(OCH3)(2) lea
ds to the oxidation of one sulfur atom to S-VI and CH3OS4N4(O)Cl is fo
rmed. The compounds were characterized by ir spectroscopy and their cr
ystal structures were determined from single crystal diffraction data
collected at -153 degrees C. The presence of S-VI in the molecule of C
H3OS4N4(O)Cl is manifested by a marked shortening of the bonds formed
by this atom as compared with S4N4Cl2 and S4N4(OCH3)(2).