J. Beddoes et al., THE BRITTLE-DUCTILE TRANSITION IN HIP CONSOLIDATED NEAR GAMMA-TIAL+W AND TIAL+CR POWDER ALLOYS, Materials science & engineering. A, Structural materials: properties, microstructure and processing, 193, 1995, pp. 324-332
The properties, deformation microstructures and fracture characteristi
cs resulting from tensile tests between 20 degrees C and 850 degrees C
are compared for Ti-48Al-2W and Ti-47.5Al-3Cr. TiAl + Cr exhibits a b
rittle-ductile transition with an elongation at 20 degrees C of 2.2% i
ncreasing to 36% at 850 degrees C. A much less pronounced brittle-duct
ile transition exists for TiAl + W, with an increase in elongation fro
m 1.3% at 20 degrees C to only 4.5% at 850 degrees C. In both alloys f
racture occurs predominantly by transgranular cleavage at low temperat
ures, changing to intergranular and then prior particle boundary failu
re with increasing temperature. High densities of deformation twins an
d 1/2[110] dislocations form in TiAl + Cr deformed at greater than or
equal to 700 degrees C. For TiAI + W much less deformation twinning oc
curs, even during tensile deformation at 850 degrees C. The inability
of TiAl + W to accommodate strain by deformation twinning eliminates t
he brittle-ductile transition that occurs for most near gamma-TiAl com
positions. TiAl + Cr attains higher fracture strength at 20 degrees C
(563 MPa) than TiAI + W (505 MPa). This improved strength is related t
o the substructure developed during HIP consolidation. The increased 2
0 degrees C ductility of TiAI + Cr is associated with a more homogeneo
us as-HTPed microstructure.