PALLADIUM-CATALYZED ASYMMETRIC HYDROPHENYLATION OF 1,4-DIHYDRO-1,4-EPOXYNAPHTHALENE

Authors
MOINET C FIAUD JC
Citation
C. Moinet et Jc. Fiaud, PALLADIUM-CATALYZED ASYMMETRIC HYDROPHENYLATION OF 1,4-DIHYDRO-1,4-EPOXYNAPHTHALENE, Tetrahedron letters, 36(12), 1995, pp. 2051-2052
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
12
Year of publication
1995
Pages
2051 - 2052
Database
ISI
SICI code
0040-4039(1995)36:12<2051:PAHO1>2.0.ZU;2-X
Abstract
Palladium-catalyzed hydrophenylation of 7-oxybenzonorbornene with phen yl iodide or triflate in the presence of formate afforded 1,4-epoxy-2- phenyl-1,2,3,4-tetrahydronaphthalene and (1R,2S*)-1,2-dihydro-2-pheny lnaphthalen-1-ol. Both product distribution and enantioselectivity for these compounds were dependent of the leaving group of the substrate and the ligand of the catalyst.