Jpg. Versleijen et al., ON THE SYNTHESIS OF BORON-SUBSTITUTED METHYL ISOCYANIDES - YANOMETHYL-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE, Tetrahedron letters, 36(12), 1995, pp. 2109-2112
Two methodes are described for the conversion of chloromethylboronates
into the corresponding formamidomethylboronates, which upon dehydrati
on provide isocyanomethylboronates. The title compound was stable enou
gh to be isolated and characterized.