IPY(2)BF(4) IS ALSO A USEFUL REAGENT FOR STEREOSPECIFIC IODINE-SILICON EXCHANGE IN OPEN-CHAIN TRIMETHYLSILYLALKENES

Authors
BARLUENGA J ALVAREZGARCIA LJ GONZALEZ JM
Citation
J. Barluenga et al., IPY(2)BF(4) IS ALSO A USEFUL REAGENT FOR STEREOSPECIFIC IODINE-SILICON EXCHANGE IN OPEN-CHAIN TRIMETHYLSILYLALKENES, Tetrahedron letters, 36(12), 1995, pp. 2153-2156
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
12
Year of publication
1995
Pages
2153 - 2156
Database
ISI
SICI code
0040-4039(1995)36:12<2153:IIAAUR>2.0.ZU;2-3
Abstract
Reaction of the title monosubstituted vinylsilanes with IPy(2)BF(4)/HB F4 gives iodoalkenes through the ipso-substitution process with stereo specific retention of configuration.