Dv. Stass et al., MANIFESTATION OF QUANTUM COHERENCE UPON RECOMBINATION OF RADICAL-ION PAIRS IN WEAK MAGNETIC-FIELDS - SYSTEMS WITH EQUIVALENT NUCLEI, Chemical physics letters, 235(5-6), 1995, pp. 511-516
Magnetosensitive radiofluorescence has been used to study the magnetic
field effect at fields of the order of hyperfine ones during the reco
mbination of spin-correlated radical ion pairs in non-polar solutions.
For radical pairs, in which hyperfine interactions are essential only
for equivalent nuclei in one of the pair partners, additional local m
axima of fluorescence intensity in characteristic 'multiple' fields we
re observed. These maxima arise from the coherent nature of the radica
l pair initial state: different stationary states interfere in the fie
lds where energy levels of the radical pair cross.