MANIFESTATION OF QUANTUM COHERENCE UPON RECOMBINATION OF RADICAL-ION PAIRS IN WEAK MAGNETIC-FIELDS - SYSTEMS WITH EQUIVALENT NUCLEI

Citation
Dv. Stass et al., MANIFESTATION OF QUANTUM COHERENCE UPON RECOMBINATION OF RADICAL-ION PAIRS IN WEAK MAGNETIC-FIELDS - SYSTEMS WITH EQUIVALENT NUCLEI, Chemical physics letters, 235(5-6), 1995, pp. 511-516
Citations number
15
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
ISSN journal
00092614
Volume
235
Issue
5-6
Year of publication
1995
Pages
511 - 516
Database
ISI
SICI code
0009-2614(1995)235:5-6<511:MOQCUR>2.0.ZU;2-E
Abstract
Magnetosensitive radiofluorescence has been used to study the magnetic field effect at fields of the order of hyperfine ones during the reco mbination of spin-correlated radical ion pairs in non-polar solutions. For radical pairs, in which hyperfine interactions are essential only for equivalent nuclei in one of the pair partners, additional local m axima of fluorescence intensity in characteristic 'multiple' fields we re observed. These maxima arise from the coherent nature of the radica l pair initial state: different stationary states interfere in the fie lds where energy levels of the radical pair cross.