SOLID-STATE MAGNETIC-RESONANCE STUDY OF KC60(THF)(X)

Authors
CHEN J SHAO QF HUANG ZE CAI RF CHEN SM
Citation
J. Chen et al., SOLID-STATE MAGNETIC-RESONANCE STUDY OF KC60(THF)(X), Chemical physics letters, 235(5-6), 1995, pp. 570-575
Citations number
18
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics letters → ACNP
ISSN journal
00092614
Volume
235
Issue
5-6
Year of publication
1995
Pages
570 - 575
Database
ISI
SICI code
0009-2614(1995)235:5-6<570:SMSOK>2.0.ZU;2-G
Abstract
Solid-state ESR and C-13 NMR spectra indicate that two electronic stat es of C-60(-) exist in KC60THF)(x) (0 < x < 1) which can be assigned t o ground (2)A (arising from the C-60(-)... K+ loose ion-pair) and (2)E (arising from the C-60(-)-K+(THF) tight ion-pair) states, originating from the splitting of the T-2(1u) state induced by Jahn-Teller distor tion.