MECHANISM OF REARRANGEMENT OF 1,8,9,10,11,11-HEXACHLORO-3-ALPHA, HA-DIHYDROXY-TRICYCLO[6.2.1.0(2,7)]UNDEC-4,9-DIENE WITH POTASSIUM T-BUTOXIDE

Authors
SURI SC RADHAKRISHNAN KV
Citation
Sc. Suri et Kv. Radhakrishnan, MECHANISM OF REARRANGEMENT OF 1,8,9,10,11,11-HEXACHLORO-3-ALPHA, HA-DIHYDROXY-TRICYCLO[6.2.1.0(2,7)]UNDEC-4,9-DIENE WITH POTASSIUM T-BUTOXIDE, Indian journal of chemistry. Sect. B: organic chemistry, including medical chemistry, 33(11), 1994, pp. 1070-1071
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Indian journal of chemistry. Sect. B: organic chemistry, including medical chemistry → ACNP
ISSN journal
03764699
Volume
33
Issue
11
Year of publication
1994
Pages
1070 - 1071
Database
ISI
SICI code
0376-4699(1994)33:11<1070:MORO1H>2.0.ZU;2-B
Abstract
The reinvestigation of reaction of 1,8,9,10,11,11-hexachloro-3 alpha, 6 pha-dihydroxytricyclo[6.2.1.0(2,7)]undec-4,9-diene (2) with t-BuOH/t -BuOK furnishes compound 6 in addition to already reported ytetracyclo [6.2.1.0(2,7).0(4,10)]undec-5-ene-9-one (4). Isolation of 6 confirms t he proposed mechanism.