Cs. Cantera et al., UNHAIRING TECHNOLOGY INVOLVING HAIR PROTECTION ADAPTATION OF A RECIRCULATION TECHNIQUE, Journal of the Society of Leather Technologists and Chemists, 79(1), 1995, pp. 12-17
The application of the hair-saving process has mainly resulted in a re
duction of the organic content and suspended-settleable solids in the
beamhouse effluent. Aiming at decreasing the volume of effluents from
unhairing and at optimizing the amount of products used in such a proc
ess in a tannery producing upholstery leather, a study concerning recy
cling was made of the effluents from a hair-saving ''chemical unhairin
g'' process that is in current use. By means of trials both at laborat
ory scale and on a pilot plant, the recirculation of an effluent (''mi
xed liquor'')-including unhairing liquid wastes and waste water from t
he first discontinuous washing-was used at the stages of alkaline cond
itioning, hair immunization, unhairing and liming. Fifteen unhairing t
rials were performed at the CITEC's pilot plant with 7 bovine hides in
each cycle; when the pelt stage was reached, the process was continue
d at the tannery. The results obtained led to the following conclusion
s: an adaptation of the recycling technique to a hair-saving process i
s applicable at the liming, immunization and unhairing stages; the fea
tures of the ''re-circulated leather'' are similar to those of the fin
ished upholstery product made by the tannery; this recycling technique
allows for an 88% reduction in the volume of unhairing wastes and for
43 and 20% reduction in the consumption of lime and sodium sulphide,
respectively.