REDUCTIVE DEHALOGENATION OF POLYHALOFLUOROCARBONS WITH TRIBUTYLTIN HYDRIDE

Authors
VANDERPUY M BELTER RK BOROWSKI RJ ELLIS LAS PERSICHINI PJ POSS AJ RYGAS TP TUNG HS
Citation
M. Vanderpuy et al., REDUCTIVE DEHALOGENATION OF POLYHALOFLUOROCARBONS WITH TRIBUTYLTIN HYDRIDE, Journal of fluorine chemistry, 71(1), 1995, pp. 59-63
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
71
Issue
1
Year of publication
1995
Pages
59 - 63
Database
ISI
SICI code
0022-1139(1995)71:1<59:RDOPWT>2.0.ZU;2-Q
Abstract
The reduction of polyhalofluorocarbons, including ClCF2CFClCF2Cl, (ClC F2CFCl)(2), ICI2(CF2)(3)CH2I and vicinal dichloroperfluorocycloalkanes , with tributyltin hydride gave the corresponding hydrofluorocarbons i n good to excellent yield. The results are compared with similar reduc tions with other reducing agents, and to tin hydride reductions of non -fluorinated analogs.