BROMO-4,4,4-TRIFLUORO-3-(TRIFLUOROMETHYL)BUT-2-ENE - SYNTHESIS AND ELECTROPHILIC REACTIVITY

Authors
MARTIN V MOLINES H WAKSELMAN C
Citation
V. Martin et al., BROMO-4,4,4-TRIFLUORO-3-(TRIFLUOROMETHYL)BUT-2-ENE - SYNTHESIS AND ELECTROPHILIC REACTIVITY, Journal of fluorine chemistry, 71(1), 1995, pp. 139-142
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
71
Issue
1
Year of publication
1995
Pages
139 - 142
Database
ISI
SICI code
0022-1139(1995)71:1<139:B-SAE>2.0.ZU;2-K
Abstract
A two-step synthesis of bromo-4,4,4-trifluoro-3-(trifluoromethyl)but-2 -ene in 35% overall yield is reported starting from commercially avail able hexafluoroacetone. The electrophilic reactivity of this new compo und towards various nucleophilic reagents has been studied. Substituti on products or ones arising from allylic rearrangement are obtained de pending on the nature of the nucleophile.