INTERACTION OF ANILINE WITH DIAZOTIZING AND NITRATING AGENTS IN CONCENTRATED SULFURIC-ACID

Authors
GORELIK MV LOMZAKOVA VI KHAMIDOVA EA SHTEIMAN VY KUZNETSOVA MG
Citation
Mv. Gorelik et al., INTERACTION OF ANILINE WITH DIAZOTIZING AND NITRATING AGENTS IN CONCENTRATED SULFURIC-ACID, Mendeleev communications, (2), 1995, pp. 64-65
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Mendeleev communications → ACNP
ISSN journal
09599436
Issue
2
Year of publication
1995
Pages
64 - 65
Database
ISI
SICI code
0959-9436(1995):2<64:IOAWDA>2.0.ZU;2-A
Abstract
The interaction of aniline with nitrosonium hydrogensulfate then with nitric acid in concentrated sulfuric acid does not occur through diazo tisation and subsequent nitration of the benzenediazonium ion, but ins tead involves nitrosonium ion catalysed nitration of anilinium ion in the para-position together with uncatalysed nitration in the meta- and para-positions followed by diazotisation on dilution with water.