NEW, NONSYMMETRICAL 2 2 PHTHALOCYANINES, ROPHTHALO-11,29(30)-DI-TERT-BUTYLDINAPHTHALOCYANIN AND IPHTHALO-11,29(30)-DI-TERT-BUTYLDINAPHTHALOCYANINE COPPER-COMPLEXES/

Authors
NEMYKIN VN SUBBOTIN NB KOSTROMINA NA VOLKOV SV
Citation
Vn. Nemykin et al., NEW, NONSYMMETRICAL 2 2 PHTHALOCYANINES, ROPHTHALO-11,29(30)-DI-TERT-BUTYLDINAPHTHALOCYANIN AND IPHTHALO-11,29(30)-DI-TERT-BUTYLDINAPHTHALOCYANINE COPPER-COMPLEXES/, Mendeleev communications, (2), 1995, pp. 71-72
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Mendeleev communications → ACNP
ISSN journal
09599436
Issue
2
Year of publication
1995
Pages
71 - 72
Database
ISI
SICI code
0959-9436(1995):2<71:NN22PR>2.0.ZU;2-6
Abstract
The reaction between tetraphenylphthalonitrile and 4-phthalonitrile or 6-terf-butylnaphthalonitrile in the presence of copper(1) chloride gi ves a non-statistical mixture of non-symmetrical phthalocyanines from which 2:2 complexes are separated; in the reaction between substituted phthalo- and naphthalonitriles the 2:2 complex was a major product. T he splitting of the Q-band in the electronic spectra depends on the di fferences in the electronic structure of the fragments of the non-symm etrical molecule.