D. Daloze et al., NEW CARDIAC-GLYCOSIDES CONTAINING 2-DEOXYHEXOSES FROM THE DEFENSIVE SECRETION OF ADULT CHRYSOLINA-BANKSI (COLEOPTERA, CHRYSOMELIDAE), Biochemical systematics and ecology, 23(2), 1995, pp. 113-119
Four new cardenolides, 2-5, have been isolated together with adenosine
from the defensive secretion of adult Chrysolina banksi beetles and t
heir structures determined by spectroscopic methods. All these glycosi
des contain periplogenin as aglycone and are characterized by the unpr
ecedented occurrence of 2-deoxy-beta-lyxo-hexopyranose and 2-deoxy-bet
a-xylo-hexopyranose. The taxonomic implications of these results are d
iscussed.