CHIRALITY PRESERVATION IN PYRROLINONE IRON TETRACARBONYL COMPLEXES - A ROUTE TO ENANTIOPURE 5-SUBSTITUTED PYRROLINONES

Authors
HOPMAN JCP HIEMSTRA H SPECKAMP WN
Citation
Jcp. Hopman et al., CHIRALITY PRESERVATION IN PYRROLINONE IRON TETRACARBONYL COMPLEXES - A ROUTE TO ENANTIOPURE 5-SUBSTITUTED PYRROLINONES, Journal of the Chemical Society, Chemical Communications, (6), 1995, pp. 617-618
Citations number
22
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
6
Year of publication
1995
Pages
617 - 618
Database
ISI
SICI code
0022-4936(1995):6<617:CPIPIT>2.0.ZU;2-W
Abstract
The enantiopure iron complex 4 reacts under the influence of BF3 . OEt (2) with allylsilanes and enol acetates through a cationic intermediat e in which the chirality of 4 is preserved, yielding enantiopure 5-sub stituted 3-pyrrolin-2-ones.