THE PREPARATION AND CRYSTAL-STRUCTURE OF A SALT WITH THE [(VO2(O(2)CME))(4)(NO3)] MONOANION

Authors
ARROWSMITH S DOVE MFA LOGAN N ANTIPIN MY
Citation
S. Arrowsmith et al., THE PREPARATION AND CRYSTAL-STRUCTURE OF A SALT WITH THE [(VO2(O(2)CME))(4)(NO3)] MONOANION, Journal of the Chemical Society, Chemical Communications, (6), 1995, pp. 627-627
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
6
Year of publication
1995
Pages
627 - 627
Database
ISI
SICI code
0022-4936(1995):6<627:TPACOA>2.0.ZU;2-#
Abstract
Acetonitrile is oxidised to acetate by vanadium(v) oxide trinitrate in the presence of tetraphenylarsonium chloride and the crystal structur e of the main reaction product, (C6H5)(4)As[V4O8(O(2)CMe)4(NO3)] 1, is solved; the anion consists of a tetravanadium(v) crown containing a g uest nitrate group in a mu 4 mode.