APPROACHES TO THE ASSEMBLY OF THE ANTIFUNGAL AGENT FR-900848 - DETERMINATION OF THE GEOMETRY OF THE DICYCLOPROPYLETHENE UNIT AND AN X-RAY CRYSTALLOGRAPHIC STUDY OF ,2-BIS[(1S,2S)-2-METHYLCYCLOPROPYL]-1,2-ETHANEDIYL 3,5-DINITROBENZOATE

Authors
BARRETT AGM KASDORF K WHITE AJP WILLIAMS DJ
Citation
Agm. Barrett et al., APPROACHES TO THE ASSEMBLY OF THE ANTIFUNGAL AGENT FR-900848 - DETERMINATION OF THE GEOMETRY OF THE DICYCLOPROPYLETHENE UNIT AND AN X-RAY CRYSTALLOGRAPHIC STUDY OF ,2-BIS[(1S,2S)-2-METHYLCYCLOPROPYL]-1,2-ETHANEDIYL 3,5-DINITROBENZOATE, Journal of the Chemical Society, Chemical Communications, (6), 1995, pp. 649-650
Citations number
5
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
6
Year of publication
1995
Pages
649 - 650
Database
ISI
SICI code
0022-4936(1995):6<649:ATTAOT>2.0.ZU;2-2
Abstract
Whitham elimination is used to prepare (Z)-1,2-bis[(1S,2S)-2-methylcyc lopropyl]ethene, which along with the corresponding E-alkene, is used as a structural model to determine that the geometry of the dicyclopro pylethene unit of FR-900848 is trans.