SINGLET OXYGEN ADDITIONS TO O[10.2.1.0(2,11).0(4,9).0(4,14).0(9,13)]PENTADECA, 5,7-DIEN-3,10-DIONES - A REMARKABLE SUBSTITUENT EFFECT ON PI-FACE SELECTIVITY INDUCED BY TRANSITION-STATE GEOMETRIC DISTORTIONS

Authors
MEHTA G SUBRAMANIAN UR PRAMANIK A CHANDRASEKHAR J NETHAJI M
Citation
G. Mehta et al., SINGLET OXYGEN ADDITIONS TO O[10.2.1.0(2,11).0(4,9).0(4,14).0(9,13)]PENTADECA, 5,7-DIEN-3,10-DIONES - A REMARKABLE SUBSTITUENT EFFECT ON PI-FACE SELECTIVITY INDUCED BY TRANSITION-STATE GEOMETRIC DISTORTIONS, Journal of the Chemical Society, Chemical Communications, (6), 1995, pp. 677-678
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
6
Year of publication
1995
Pages
677 - 678
Database
ISI
SICI code
0022-4936(1995):6<677:SOATO>2.0.ZU;2-O
Abstract
Face selectivity in singlet oxygen addition to a rigid polycyclic dien e is reversed by sterically neutral 1,4-substitution, an effect attrib uted to lone pair repulsions induced by out-of-plane bending at the tr ansition state.