SELF-ASSEMBLY OF HOMOCHIRAL DOUBLE HELIX AND SIDE-BY-SIDE HELIX CONFORMERS OF A DOUBLE-STRANDED DISILVER(I)-TETRA(TERTIARY PHOSPHINE) COMPLEX

Authors
AIREY AL SWIEGERS GF WILLIS AC WILD SB
Citation
Al. Airey et al., SELF-ASSEMBLY OF HOMOCHIRAL DOUBLE HELIX AND SIDE-BY-SIDE HELIX CONFORMERS OF A DOUBLE-STRANDED DISILVER(I)-TETRA(TERTIARY PHOSPHINE) COMPLEX, Journal of the Chemical Society, Chemical Communications, (6), 1995, pp. 695-696
Citations number
20
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
6
Year of publication
1995
Pages
695 - 696
Database
ISI
SICI code
0022-4936(1995):6<695:SOHDHA>2.0.ZU;2-I
Abstract
Optically pure -Ph(2)PCH(2)CH(2)P(Ph)CH2CH2P(Ph)CH(2)CH(2)PPh(2), (S,S )-1, spontaneously self-assembles into left-handed double-stranded D-2 -double helix and C-2-side-by-side helix conformers of the disilver(I) cation; the crystal and molecular structure of Lambda-(-)-[Ag-2{(R,R) -1}(2)][PF6](2) is reported.