SYNTHESIS OF ALLENYL-STANNANES AND ALKYNYL-STANNANES BY REDUCTION OF ALLENYL-CHLOROSTANNANES AND ALKYNYL-CHLOROSTANNANES

Authors
LASSALLE L JANATI T GUILLEMIN JC
Citation
L. Lassalle et al., SYNTHESIS OF ALLENYL-STANNANES AND ALKYNYL-STANNANES BY REDUCTION OF ALLENYL-CHLOROSTANNANES AND ALKYNYL-CHLOROSTANNANES, Journal of the Chemical Society, Chemical Communications, (6), 1995, pp. 699-700
Citations number
27
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
6
Year of publication
1995
Pages
699 - 700
Database
ISI
SICI code
0022-4936(1995):6<699:SOAAAB>2.0.ZU;2-Y
Abstract
Allenyl- 1a,b and alkynyl-stannanes 2a-c are synthesized by reaction o f the corresponding allenyl- and alkynyl-tributylstannanes with tin te trachloride or dichlorodimethylstannane followed by a chemoselective r eduction of the formed chlorostannanes with tributylstannane in the pr esence of duroquinone or galvinoxyl, a radical inhibitor.