GLYCINE C-60 ADDUCT AND ITS RARE-EARTH COMPLEXES

Authors
ZHOU DJ GAN LB XU LB LUO CP HUANG CH
Citation
Dj. Zhou et al., GLYCINE C-60 ADDUCT AND ITS RARE-EARTH COMPLEXES, Fullerene science and technology, 3(2), 1995, pp. 127-131
Citations number
15
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical","Material Science
Journal title
Fullerene science and technology → ACNP
ISSN journal
1064122X
Volume
3
Issue
2
Year of publication
1995
Pages
127 - 131
Database
ISI
SICI code
1064-122X(1995)3:2<127:GCAAIR>2.0.ZU;2-D
Abstract
Glycine sodium salt reacts with C-60 to give a water soluble derivativ e 1, acidification of which produces a less soluble product 2. When co mpound 2 is treated with Ln(ClO4)(3) (Ln=La,Y) in several different mo lar ratios, insoluble rare earth complexes: C-60(Gly)(x)Ln(x/3)(OH)(y) (H2O)(z) (x=7-8,y=4-6,z=2-6) were obtained. These new compounds have b een characterized by IR,TG-DTA and XPS spectra.