SYNTHESIS OF A POLYNORBORNENE CONTAINING 3,5-DI-TERT-BUTYL-4-HYDROXYBENZOYL GROUP

Authors
TLENKOPATCHEV MA MIRANDA E CANSECO MA GAVINO R OGAWA T
Citation
Ma. Tlenkopatchev et al., SYNTHESIS OF A POLYNORBORNENE CONTAINING 3,5-DI-TERT-BUTYL-4-HYDROXYBENZOYL GROUP, Polymer bulletin, 34(4), 1995, pp. 385-391
Citations number
17
Categorie Soggetti
Polymer Sciences
Journal title
Polymer bulletin → ACNP
ISSN journal
01700839
Volume
34
Issue
4
Year of publication
1995
Pages
385 - 391
Database
ISI
SICI code
0170-0839(1995)34:4<385:SOAPC3>2.0.ZU;2-I
Abstract
A new polynorbornene derivative was synthesized by ring-opening metath esis polymerization (ROMP) of t-butyl-4-hydroxy-benzoyl)oxy]methyl}-2- norbornene (BHBN) using Ru- and Os-based catalysts. The structure and properties of the poly(BHBN) were characterized by NMR, IR, DTA, DSC, and GPC. It was shown that ROMP leads to the formation of high molecul ar weight polynorbornene derivatives containing the stabilizing group.