STUDY OF THE ISOTOPE EFFECT IN THE ISOTOPE-EXCHANGE REACTION BETWEEN PU-IV AND PU-III BY EXTRACTION REDOX CHROMATOGRAPHY

Authors
NIKITENKO SI DZYUBENKO VI
Citation
Si. Nikitenko et Vi. Dzyubenko, STUDY OF THE ISOTOPE EFFECT IN THE ISOTOPE-EXCHANGE REACTION BETWEEN PU-IV AND PU-III BY EXTRACTION REDOX CHROMATOGRAPHY, Russian chemical bulletin, 43(9), 1994, pp. 1469-1470
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
43
Issue
9
Year of publication
1994
Pages
1469 - 1470
Database
ISI
SICI code
1066-5285(1994)43:9<1469:SOTIEI>2.0.ZU;2-4
Abstract
The equilibrium isotope effect in the isotope exchange reaction betwee n Pu-IV extracted with tributyl phosphate and Pu-III in an aqueous nit ric acid solution has been studied by extraction chromatography. For t he Pu-238/242 isotope pair the isotope separation coefficient (alpha) at 25 degrees C has been found to be 1.0022+/-0.0005.