SYNTHESIS OF BROMINATED 2-(TERT-BUTYL-NNO-AZOXY)ANILINES

Authors
CHURAKOV AM SMIRNOV OY IOFFE SL STRELENKO YA TARTAKOVSKY VA
Citation
Am. Churakov et al., SYNTHESIS OF BROMINATED 2-(TERT-BUTYL-NNO-AZOXY)ANILINES, Russian chemical bulletin, 43(9), 1994, pp. 1532-1535
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
43
Issue
9
Year of publication
1994
Pages
1532 - 1535
Database
ISI
SICI code
1066-5285(1994)43:9<1532:SOB2>2.0.ZU;2-5
Abstract
2-(tert-Butyl-NNO-azoxy)aniline was prepared by selective reduction of 2-(tert-butyl-NNO-azoxy)nitrobenzene. Its bromination yielded the cor responding para-bromo- and ortho,para-dibromoanilines (3a,b). meta-Bro moanilines (6a,b) were synthesized by selective replacement of the ort ho-bromine atoms in ortho,para-bromo(tert-butylazoxy)benzene (5a,b) by ammonia in toluene under pressure.