EFFECT OF ELECTRONIC INTERACTIONS BETWEEN DOUBLE-BONDS ON THE CONFORMATIONAL FLEXIBILITY OF 1,4-CYCLOHEXADIENE

Authors
SHISHKIN OV POLYAKOVA AS PREZHDO OV DESENKO SM ORLOV VD STRUCHKOV YT
Citation
Ov. Shishkin et al., EFFECT OF ELECTRONIC INTERACTIONS BETWEEN DOUBLE-BONDS ON THE CONFORMATIONAL FLEXIBILITY OF 1,4-CYCLOHEXADIENE, Russian chemical bulletin, 43(9), 1994, pp. 1587-1588
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
43
Issue
9
Year of publication
1994
Pages
1587 - 1588
Database
ISI
SICI code
1066-5285(1994)43:9<1587:EOEIBD>2.0.ZU;2-9
Abstract
The electronic structure of 1,4-cyclohexadiene for various angles betw een the double bond planes has been calculated by the AMI method. The effects of through-bond and through-space interactions, which result i n flattening and unflattening, respectively, are oppositely directed. These effects are specified for various bending angles. In addition to steric factors, electronic factors affect the conformational flexibil ity of 1,4-cyclohexadiene.