STRONTIUM DIIRON(III) PYROPHOSPHATE

Authors
BOUTFESSI A BOUKHARI A HOLT EM
Citation
A. Boutfessi et al., STRONTIUM DIIRON(III) PYROPHOSPHATE, Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 346-348
Citations number
10
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
3
Pages
346 - 348
Database
ISI
SICI code
0108-2701(1995)51:<346:SDP>2.0.ZU;2-8
Abstract
SrFe2III(P2O7)(2) [strontium diiron(III) bis(diphosphate)] was prepare d using high-temperature fusion and was found to crystallize in the tr iclinic space group P $($) over bar$$ 1. The Fe-III atoms have distort ed octahedral coordination geometry [average Fe-O 1.996(3) Angstrom] a nd the Sr atoms are in sites of eightfold coordination [average Sr-O 2 .739 (3) Angstrom]. Columns of alternating Sr and Fe atoms are observe d at x = 1/2, y = 0, whereas columns of widely separated Fe atoms are seen at x = 0, y = 1/2.