CS6CL3[FE(CN)(6)]CENTER-DOT-H2O - A MIXED-ANION SALT

Authors
CAPPARELLI MV MURGICH J
Citation
Mv. Capparelli et J. Murgich, CS6CL3[FE(CN)(6)]CENTER-DOT-H2O - A MIXED-ANION SALT, Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 356-358
Citations number
19
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
3
Pages
356 - 358
Database
ISI
SICI code
0108-2701(1995)51:<356:C-AMS>2.0.ZU;2-8
Abstract
Hexacaesium trichloride hexacyanoferrate(III) monohydrate, Cs6Cl3[Fe(C N)(6)].H2O, is a novel type of compound which contains two different a nions. The crystal structure consists of alternating layers, A {Cs+, C l-, [Fe(CN)(6)](3-), H2O} and B (Cs+, Cl-), stacked perpendicularly to the b axis. The octahedral complex ion has m point symmetry. The wate r molecules of solvation are disordered and form hydrogen bonds (O-H . .. Cl and O-H ... N) within layer A. The Cs+ ions have coordination nu mbers six to eight.