E-P,P'](4-MORPHOLINECARBODITHIOATO-S,S')NICKEL(II) PERCHLORATE DICHLOROMETHANE SOLVATE

Authors
AKILAN R SIVAKUMAR K VENKATACHALAM V RAMALINGAM K CHINNAKALI K FUN HK
Citation
R. Akilan et al., E-P,P'](4-MORPHOLINECARBODITHIOATO-S,S')NICKEL(II) PERCHLORATE DICHLOROMETHANE SOLVATE, Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 368-370
Citations number
16
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
3
Pages
368 - 370
Database
ISI
SICI code
0108-2701(1995)51:<368:EPD>2.0.ZU;2-T
Abstract
The crystal structure determination of the title compound, [Ni(C5H8NOS 2)(C26H24P2)]ClO4.CH2Cl2, indicates that the morpholine ring adopts tw o orientations related by a rotation of 180 degrees. The perchlorate g roup is highly disordered and forms close contacts with both the morph olino ligand and the dichloromethane solvent molecule, However, there are no short contacts between the dichloromethane solvent and the comp lex molecule.