COMPLEX BETWEEN RHODIUM(II) AND A [1,4]TH IAZEPINE DERIVATIVE - SYNTHESIS AND CRYSTAL-STRUCTURE OF BENZO[B,F][1,4]THIAZEPINE-N-10]RHODIUM(II))(RH-RH)

Authors
LEMOINE P TOMAS A VIOSSAT B METTEY Y VIERFOND JM
Citation
P. Lemoine et al., COMPLEX BETWEEN RHODIUM(II) AND A [1,4]TH IAZEPINE DERIVATIVE - SYNTHESIS AND CRYSTAL-STRUCTURE OF BENZO[B,F][1,4]THIAZEPINE-N-10]RHODIUM(II))(RH-RH), Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 377-380
Citations number
17
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
3
Pages
377 - 380
Database
ISI
SICI code
0108-2701(1995)51:<377:CBRAA[>2.0.ZU;2-K
Abstract
The unit cell of the title compound, tetrakis(mu-acetato-O:O')bis{[ mi nodibenzo[b,f][1,4]thiazepine-N-10]]rhodium(II)} (Rh-Rh), [Rh(C2H3O2)( 4)(C13H10-N2S)(2)], contains four discrete dimer molecules which have an inversion centre. The Rh-Rh distance [2.402 (2) Angstrom and other parameters for the rhodium acetate cage show no major deviations from those reported in the literature. The thiazepine is in a boat conforma tion. The dihedral angle between the two aromatic rings is 96.7(5)degr ees. There are no hydrogen bonds.