A NOVEL STRUCTURE OF (L-ASPARTATO)(1,10-PHENANTHROLINE)COPPER(II) HYDRATE

Citation
Rf. Baggio et al., A NOVEL STRUCTURE OF (L-ASPARTATO)(1,10-PHENANTHROLINE)COPPER(II) HYDRATE, Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 382-385
Citations number
2
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
3
Pages
382 - 385
Database
ISI
SICI code
0108-2701(1995)51:<382:ANSO(H>2.0.ZU;2-G
Abstract
The title compound, [CU(C4H5NO4)(C12H8N2)].3.5H(2)O, consists of two t ypes of different pentacoordinate copper complex: one monomeric, with the aspartate group acting as a tridentate ligand, and the other polym eric, with the aspartate group bridging two different copper centers. The whole structure is held together by a complex hydrogen-bonding sch eme involving the water molecules of solvation.