TRIS(3,5-DIMETHYLPYRAZOL-1-YL)METHYLSILANE

Authors
VEPACHEDU S STIBRANY RT KNAPP S POTENZA JA SCHUGAR HJ
Citation
S. Vepachedu et al., TRIS(3,5-DIMETHYLPYRAZOL-1-YL)METHYLSILANE, Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 423-426
Citations number
13
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
51
Year of publication
1995
Part
3
Pages
423 - 426
Database
ISI
SICI code
0108-2701(1995)51:<423:T>2.0.ZU;2-R
Abstract
The structure consists of discrete molecules of tris-(3, 5-dimethylpyr azol-1-yl)methylsilane, C16H24N6Si, that exhibit distorted tetrahedral SiN(pyrazole)(3)C geometry about the Si atom. The Si and methyl C ato ms lie on threefold axes. The C-Si-N and N-Si-N bond angles are 111.3( 2) and 107.5(2)degrees, respectively, while the Si-N bond length is 1. 745 (5) Angstrom. The present work provides the first reported structu re containing an Si-N(pyrazole) linkage.