X-RAY FLUORESCENT AND EXAFS STUDIES OF THE ELECTRONIC AND SPATIAL STRUCTURE OF DIALKYL SULFIDES AND THEIR PDCL2 COMPLEXES IN EXTRACTION SYSTEMS

Authors
ERENBURG SB MAZALOV LN BAUSK NV DROZDOVA MK
Citation
Sb. Erenburg et al., X-RAY FLUORESCENT AND EXAFS STUDIES OF THE ELECTRONIC AND SPATIAL STRUCTURE OF DIALKYL SULFIDES AND THEIR PDCL2 COMPLEXES IN EXTRACTION SYSTEMS, Journal of structural chemistry, 35(4), 1994, pp. 517-522
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Journal of structural chemistry → ACNP
ISSN journal
00224766
Volume
35
Issue
4
Year of publication
1994
Pages
517 - 522
Database
ISI
SICI code
0022-4766(1994)35:4<517:XFAESO>2.0.ZU;2-Z
Abstract
SKalpha, SKbeta, ClKalpha, ClKbeta, and PdL(beta 2) X-ray fluorescent and PdK EXAFS spectra were obtained for some organic solutions of dial kyl sulfide complexes with palladium chloride. Solvent effects on the electronic and spatial structure of complexes in solution are discusse d In the benzene solution of [PdCl(2)2(C6H13)(2)S] complex molecules i nteract with solvent molecules along a coordinate that is perpendicula r to the plane of the complex molecule.